See stereodivergent on Wiktionary
{ "etymology_templates": [ { "args": { "1": "en", "2": "stereo", "3": "divergent" }, "expansion": "stereo- + divergent", "name": "prefix" } ], "etymology_text": "From stereo- + divergent.", "head_templates": [ { "args": { "1": "-" }, "expansion": "stereodivergent (not comparable)", "name": "en-adj" } ], "lang": "English", "lang_code": "en", "pos": "adj", "senses": [ { "categories": [ { "kind": "other", "name": "English entries with incorrect language header", "parents": [ "Entries with incorrect language header", "Entry maintenance" ], "source": "w" }, { "kind": "other", "name": "English terms prefixed with stereo-", "parents": [], "source": "w" }, { "kind": "other", "name": "Pages with 1 entry", "parents": [], "source": "w" }, { "kind": "other", "name": "Pages with entries", "parents": [], "source": "w" }, { "kind": "topical", "langcode": "en", "name": "Organic chemistry", "orig": "en:Organic chemistry", "parents": [ "Chemistry", "Sciences", "All topics", "Fundamental" ], "source": "w" } ], "examples": [ { "ref": "2015 June 10, Ruth Dorel, Antonio M. Echavarren, “Gold-Catalyzed Reactions via Cyclopropyl Gold Carbene-like Intermediates”, in The Journal of Organic Chemistry, volume 80, →DOI:", "text": "This cascade cyclization process is ideally suited for the total syntheses of sesquiterpenes (−)-4α,7α-aromadendranediol ( 92 ), (−)-4β,7α-aromadendranediol ( 93 ), and (−)-epiglobulol ( 94 ) from a single dienyne 84b by using a stereodivergent gold(I)-catalyzed reaction as the key step (Scheme 24 ). 115 In the absence of any external nucleophile, cyclopropyl gold(I) carbene intermediate 89 undergoes a 1,5-OBn migration followed by intramolecular cyclopropanation to form tricyclic compound 88b, which is the precursor of 93 and 94 .", "type": "quote" } ], "glosses": [ "That produces different chiral forms of the same compound" ], "id": "en-stereodivergent-en-adj-I88WRmi8", "links": [ [ "organic chemistry", "organic chemistry" ], [ "different", "different" ], [ "chiral", "chiral" ] ], "raw_glosses": [ "(organic chemistry) That produces different chiral forms of the same compound" ], "related": [ { "word": "stereodivergence" } ], "tags": [ "not-comparable" ], "topics": [ "chemistry", "natural-sciences", "organic-chemistry", "physical-sciences" ] } ], "word": "stereodivergent" }
{ "etymology_templates": [ { "args": { "1": "en", "2": "stereo", "3": "divergent" }, "expansion": "stereo- + divergent", "name": "prefix" } ], "etymology_text": "From stereo- + divergent.", "head_templates": [ { "args": { "1": "-" }, "expansion": "stereodivergent (not comparable)", "name": "en-adj" } ], "lang": "English", "lang_code": "en", "pos": "adj", "related": [ { "word": "stereodivergence" } ], "senses": [ { "categories": [ "English adjectives", "English entries with incorrect language header", "English lemmas", "English terms prefixed with stereo-", "English terms with quotations", "English uncomparable adjectives", "Pages with 1 entry", "Pages with entries", "en:Organic chemistry" ], "examples": [ { "ref": "2015 June 10, Ruth Dorel, Antonio M. Echavarren, “Gold-Catalyzed Reactions via Cyclopropyl Gold Carbene-like Intermediates”, in The Journal of Organic Chemistry, volume 80, →DOI:", "text": "This cascade cyclization process is ideally suited for the total syntheses of sesquiterpenes (−)-4α,7α-aromadendranediol ( 92 ), (−)-4β,7α-aromadendranediol ( 93 ), and (−)-epiglobulol ( 94 ) from a single dienyne 84b by using a stereodivergent gold(I)-catalyzed reaction as the key step (Scheme 24 ). 115 In the absence of any external nucleophile, cyclopropyl gold(I) carbene intermediate 89 undergoes a 1,5-OBn migration followed by intramolecular cyclopropanation to form tricyclic compound 88b, which is the precursor of 93 and 94 .", "type": "quote" } ], "glosses": [ "That produces different chiral forms of the same compound" ], "links": [ [ "organic chemistry", "organic chemistry" ], [ "different", "different" ], [ "chiral", "chiral" ] ], "raw_glosses": [ "(organic chemistry) That produces different chiral forms of the same compound" ], "tags": [ "not-comparable" ], "topics": [ "chemistry", "natural-sciences", "organic-chemistry", "physical-sciences" ] } ], "word": "stereodivergent" }
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This page is a part of the kaikki.org machine-readable All languages combined dictionary. This dictionary is based on structured data extracted on 2024-12-03 from the enwiktionary dump dated 2024-11-21 using wiktextract (94ba7e1 and 5dea2a6). The data shown on this site has been post-processed and various details (e.g., extra categories) removed, some information disambiguated, and additional data merged from other sources. See the raw data download page for the unprocessed wiktextract data.
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