"stereodivergent" meaning in All languages combined

See stereodivergent on Wiktionary

Adjective [English]

Etymology: From stereo- + divergent. Etymology templates: {{prefix|en|stereo|divergent}} stereo- + divergent Head templates: {{en-adj|-}} stereodivergent (not comparable)
  1. (organic chemistry) That produces different chiral forms of the same compound Tags: not-comparable Categories (topical): Organic chemistry Related terms: stereodivergence
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          "ref": "2015 June 10, Ruth Dorel, Antonio M. Echavarren, “Gold-Catalyzed Reactions via Cyclopropyl Gold Carbene-like Intermediates”, in The Journal of Organic Chemistry, volume 80, →DOI:",
          "text": "This cascade cyclization process is ideally suited for the total syntheses of sesquiterpenes (−)-4α,7α-aromadendranediol ( 92 ), (−)-4β,7α-aromadendranediol ( 93 ), and (−)-epiglobulol ( 94 ) from a single dienyne 84b by using a stereodivergent gold(I)-catalyzed reaction as the key step (Scheme 24 ). 115 In the absence of any external nucleophile, cyclopropyl gold(I) carbene intermediate 89 undergoes a 1,5-OBn migration followed by intramolecular cyclopropanation to form tricyclic compound 88b, which is the precursor of 93 and 94 .",
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This page is a part of the kaikki.org machine-readable All languages combined dictionary. This dictionary is based on structured data extracted on 2024-12-03 from the enwiktionary dump dated 2024-11-21 using wiktextract (94ba7e1 and 5dea2a6). The data shown on this site has been post-processed and various details (e.g., extra categories) removed, some information disambiguated, and additional data merged from other sources. See the raw data download page for the unprocessed wiktextract data.

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